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刘博 博士

发布者:  发布时间:2017年07月06日 09:36

刘博:男,198911月出生,博士,教授。2010年毕业于吉林大学高分子材料科学与工程学院,获得工学学士学位;同年联合培养于吉林大学材料科学与工程学院和中科院长春应用化学研究所,于2015年获得工学博士学位。20162月至今为新加坡南洋理工大学生物化学与工程学院博士后,开展新型高效抗菌离子液体的合成。现在长沙理工大学材料科学与工程学院工作,主要从事新型聚离子液体在生物抗菌和电解液方向的应用。

研究领域和兴趣:

1. 以多组分反应(Debus-Radziszewski反应, Passerini反应, Schiff-base 反应,Ugi反应和亚胺化反应等)为基础,在温和的反应、低成本条件下,构筑具有高效抗菌性能的离子液体;离子液体作为电解液在液流电池的应用;

2. 设计合成金属催化剂,通过对烯烃单体的聚合的手性位点控制,制备具有高立体规整度的聚合物。探讨聚合物的立体选择性与抗菌选择性之间的内在联系;

3. 通过芳香胺和芳香酸酐亚胺化反应开发均一分布的聚酰亚胺,并探讨聚合物极性对分散碳纳米管的性能影响,进而制备具有高机械强度和耐高温聚合物复合材料。

科研成果和参与项目:

作为团队核心成员获得首批湖南省团队百人计划项目。目前,申请国际专利2项,国家发明专利2项,已获得授权专利2项。在AngewChemInt Edit, Chemistry of materials, Macromolecules, Chemical Communications, Organometallics等国际期刊上发表科研论文近20篇。其中以第一作者发表论文10篇。首次利用稀土催化剂对可再生单体月桂烯及其衍生物亚甲基环戊二烯实现高选择性高活性配位可控聚合,也为聚烯烃的可持续发展提供了一种新的思路。

近五年来,博士期间先后承担两项国家自然科学基金可持续性聚合催化用与先进可生物再生聚合物的合成(90万元)和稀土配位催化异戊二烯、丁二烯、苯乙烯选择性三元共聚合制备集成橡胶(85万元);博后期间承担Novel antimicrobial hydrogel formulations for biomedical devices(新型抗菌水凝胶在生物医用器件的应用,1500万元),Selective therapy with cationic antimicrobial biomacromolecules(阳离子抗菌生物大分子的选择性医疗,5000万元),Hierarchical composite research(多级复合材料研究,500万元),主持并负责Procter & Gamble(宝洁公司)联合项目阳离子聚合物在表面活性性下的选择性杀菌(cationic polymers selective antimicrobial with anionic surfactant500万元)。在国内外学术刊物上发表论文20余篇,申请国家发明专利,PCT专利和美国专利共4项。近年来,作为邀请审稿人多次为ACS NanoACS Applied Materials & InterfacesBiomacromolecules进行评审工作。

 

近五年主要论著:

发表论文:

1. Bo Liu and Dongmei Cui, Coordination Polymerization of Renewable 3Methylenecyclopentene with RareEarth Metal Precursors, AngewChemInt Edit, 2017, 56, 4560–4564

2. Bo Liu, and Chengyin LiuChan Bee Eng, Mary,Using novel PLA-PI-PLA and PMCP-PI-PMCP triblock copolymers as Dispersants of Single-Walled Carbon Nanotubes for Reinforcement of Epoxy Composites, Polymer Chemistry, 2017, accepted

3. Bo Liu, Lei Li, Guangping Sun, Jingrao Liu, Meiyan Wang, Shihui Li and Dongmei Cui,* Macromolecules, 2014, 47, 4971−4978. 3,4-Polymerization of Isoprene by Using NSN- and NPN-Ligated Rare Earth Metal Precursors: Switching of Stereo Selectivity and Mechanism

4. Bo Liu, Lei Li, Guangping Sun, Dongtao Liu, Shihui Li and Dongmei Cui,* Chem. Commun., 2015, 51, 1039–1041. Isoselective 3,4-(co)Polymerization of Bio-renewable Myrcene Using NSN-ligated Rare-earth Metal Precursor: An Approach To a New Elastomer

5. Bo Liu, Guangping Sun, Shihui Li, Dongtao Liu and Dongmei Cui,* Organometallics, 2015, 34: 4063-4068. Isoprene Polymerization with Iminophosphonamide Rare-Earth Metal Alkyl Complexes: Influence of Metal-Size on the Regio and Stereoselectivity

6. Chengyin LiuBo Liu, Chan Bee Eng, Mary, Polymer Chemistry, 2017, 8, 674-681 Synthesis of Polycaprolactone-Polyimide-Polycaprolactone Triblock Copolymers via a 2-step Sequential Copolymerization and their Application as Carbon Nanotube Dispersants (共同一作,封面)

7. Bo Liu, Shihui Li, Dongtao Liu, Guangping Sun and Dongmei Cui,* Chinese J PolymSci, 2015, Highly Trans-1,4-Selective (Co)Polymerizations of Myrcene and Isoprene by a Lanthanum dialkyl complex that Bears a Imidophosphonamido Ligand

8. Bo Liu, Shihui Li, Danfeng Li, KuiLv, Guangping Sun and Dongmei Cui,* Chinese J Applied Chem, 2012, 29, 1394–1398. Highly 1,2-Selective Polymerization of 1,3-Butadiene with Rare-earth Metal Bis(alky)s Bearing an Iminophosphonamide Ligand

9. Bo Liu, Chunmei Jiang, Chunling Zhang, Xuetao Bai and Jianxin Mu High Performance Polymers 2012, 24, 747–755. Octasilsesquioxane-reinforced TMBP Epoxy Nanocomposites: Characterization of Thermal, Flame-retardant, and Morphological Properties

10. Bo Liu, Baoyu Han, Chunling Zhang, Shihui Li, Guangping Sun and Dongmei Cui,* Chinese J PolymSci, 2015, 33, 792–796. Renewable Myrcene Polymerization Initiated by Lutetium Alkyl Complexes Ligated by Imidophosphonamido Ligand (封面)

11. Lei Li, Bo Liu, Dongtao Liu, Chunji Wu, Shihui Li, and Dongmei Cui,* Organometallics, 2014, 24, 6474–6480. Copolymerization of ε-Caprolactone and L-Lactide Catalyzed by Multinuclear Aluminum Complexes: An Immortal Approach

专利:

1. Chan Bee Eng, Mary, 刘博, Poly(Alkylated Imidazolium) Salts, US patent 62/486,613 (美国专利) (第一作者为导师)

2. 崔冬梅,刘博, 国家发明专利, 201410634701.0, 2014. 一种3,4聚月桂烯的制备方法 (第一作者为导师)

3. 崔冬梅,刘博, 国家发明专利, 201310689095.8, 2013. 稀土催化剂合成在结晶性3,4聚异戊二烯的应用 (PCT专利) (第一作者为导师)

4. 张春玲,刘博, 国家发明专利, 201110381870.4, 2011. 环氧树脂与笼型倍半硅氧烷杂化材料的制备(第一作者为导师)

会议论文:

1. Bo Liu and Chan Bee Eng, Mary,* Poster, 2016. International Conference on cellular&molecular bioengineer, Singapore

2. Bo Liu and Dongmei Cui,* Poster, 2014. International Workshop on Catalytic Olefin Polymerization and High Performance Polyolefins, Shanghai

3. Bo Liu and Dongmei Cui,* Poster, 2013. The 2nd Grubbs Symposium on Polymer & Catalysis, Ningbo

4. Bo Liu and Dongmei Cui,* Poster, 2012. National Organometallic Symposium of China, Beijing

5. Bo Liu, and Chunling Zhang,* Abstract, 2012. China Flame Retardant Academic Annual Meeting, Xiamen

 

Emaillbb1107@126.com

通讯地址:(邮政编码410114)湖南省长沙市雨花区万家丽南路二段960号材料科学与工程学院


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